ASTM A335 Alloy Seamless Steel Pipes

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ASTM A335 Alloy Seamless Steel Pipes
ASTM A335 is a standard specification for seamless ferritic alloy-steel pipes designed for high-temperature service. These pipes are manufactured from chromium-molybdenum (Cr-Mo) alloy steels, which provide enhanced strength, resistance to oxidation (scaling), and creep resistance at elevated temperatures compared to carbon steel pipes. Common grades include P5 (5Cr-0.5Mo), P9 (9Cr-1Mo), P11 (1.25Cr-0.5Mo), P22 (2.25Cr-1Mo), and P91 (9Cr-1Mo-V). The seamless construction ensures reliability under high pressure and temperature conditions.

Primarily used in power generation boilers, refineries, petrochemical plants, and high-pressure process piping systems, ASTM A335 pipes handle critical applications such as steam lines, superheaters, heat exchangers, and hydrocarbon processing units. They operate effectively in temperatures ranging from 400°C to 650°C+ (depending on grade). The standard mandates strict requirements for chemical composition, heat treatment (normalization/tempering), mechanical properties (tensile/yield strength), hydrostatic testing, and non-destructive examination to ensure performance in demanding environments where corrosion, thermal stress, and pressure are major concerns.

Chemical Composition

Grade

P-5

P-9

P-11

P-22

P-91

P-91 shall also
 include the following:

Element

UNS Designation

K41545

S50400

K11597

K21590

K91560

Carbon

0.15 max

0.15 max

0.05 – 0.15

0.05 – 0.15

0.08 – 0.12

V at 0.18 – 0.25

Manganese

0.30 – 0.60

0.30 – 0.60

0.30 – 0.60

0.30 – 0.60

0.30 – 0.60

N at 0.030 – 0.070

Phosphorous, max

0.025

0.025

0.025

0.025

0.02

Ni at 0.40 max

Sulfur, max

0.025

0.025

0.025

0.025

0.01

Al at 0.02 max

Silicon

0.50 max

0.25 – 1.00

0.50 – 1.00

0.50 max

0.20 -0.50

Cb at 0.06 – 0.10

Chromium

4.00 – 6.00

8.00 – 10.00

1.00 – 1.50

1.90 – 2.60

8.00 – 9.50

Ti at 0.01 max

Molybdenum

0.45 -0.65

0.90 – 1.10

0.44 – 0.65

0.87 – 1.13

0.85 – 1.05

Zr at 0.01 max

TensileTest

Seamless

P-5

P-9

P-11

P-22

P-91

P91 shall not have a hardness not exceeding 250 HB/265 HV [25HRC].

Tensile Strength, min., psi

ksi

60

60

60

60

85

MPa

415

415

415

415

585

Yield Strength, min., psi

ksi

30

30

30

30

60

MPa

205

205

205

205

415

Other Mechanical Test

Transverse or Longitudinal Tension Test and Flattening Test, Hardness Test, or Bend Test

For material heat treated in a batch-type furnace, tests shall be made on 5% of the pipe from each treated lot. for small lots, at least one pipe shall be tested.

For material heat treated by the continuous process, tests shall be made on a sufficient number of pipe to constitute 5% of the lot, but in no case less than 2 pipe.

Notes for Hardness Test:

P91 shall not have a hardness not exceeding 250 HB/265 HV [25HRC].

Notes for Bend Test:

For pipe whose diameter exceeds NPS 25 and whose diameter to wall thickness ratio is 7.0 or less shall be subjected to the bend test instead of the flattening test.

Other pipe whose diameter equals or exceeds NPS 10 may be given the bend test in place of the flattening test subject to the approval of the purchaser.

The bend test specimens shall be bent at room temperature through 180 without cracking on the outside of the bent portion.

The inside diameter of the bend shall be 1 inch [25 mm].

Hydrostatic test

Each length of pipe shall be Hydro tested, at option of manufacture, nondestructive electric testing can be used.

 

Heat Treatment

P5, P9, P11, and P22

Grade

Heat Treatment Type

Normalizing Temperature Range F [C]

Subcritical Annealing or Tempering Temperature Range F [C]

P5 (b,c)

Full or Isothermal Anneal

Normalize and Temper

*****

1250 [675]

Subcritical Anneal (P5c only)

*****

1325 – 1375 [715 – 745]

P9

Full or Isothermal Anneal

Normalize and Temper

*****

1250 [675]

P11

Full or Isothermal Anneal

Normalize and Temper

*****

1200 [650]

P22

Full or Isothermal Anneal

Normalize and Temper

*****

1250 [675]

P91

Normalize and Temper

1900-1975 [1040 – 1080]

1350-1470 [730 – 800]

Quench and Temper

1900-1975 [1040 – 1080]

1350-1470 [730 – 800]

Permissible Variation in Wall Thickness

NPS [DN] Designator

Tolerance, % from Specified

Over

Under

1/8 to 2 1/2 [6 to 65] incl., all t/D ratios

20.00%

12.50%

Above 2 1/2 [65], t/D or = 5%

22.50%

12.50%

Above 2 1/2 [65], t/D 5%

15.00%

12.50%

(t = Specified Wall Thickness; D = Specified Outside Diameter)

Elongation Requirement

Calculated Minimum Elongation Values

Elongation in 2 in. or 50 mm, min %

Wall Thickness

P5, P9, P11, P22

P91

in.

mm

Longitudinal

Transverse

Longitudinal

5/16 (0.312)

8

30

20

20

9/32 (0.281)

7.2

28

19

19

1/4 (0.250)

6.4

27

18

18

7/32 (0.219)

5.6

26

17

3/16 (0.188)

4.8

24

16

5/32 (0.156)

4

22

15

7/8 (0.125)

3.2

21

14

3/32 (0.094)

2.4

20

13

1/18 (0.062)

1.6

18

12

Permissible Variations in Outside Diameter

NPS [DN] Designator

Over

Under

in.

mm

in.

mm

1/8 to 1 1/2 [6 to 40], incl.

1/64 (0.015)

0.4

1/64 (0.015)

0.4

Over 1 1/2 to 4 [40 to 100], incl.

1/32 (0.031)

0.79

1/32 (0.031)

0.79

Over 4 to 8 [100 to 200], incl.

1/16 (0.062)

1.59

1/32 (0.031)

0.79

Over 8 to 12 [200 to 300], incl.

3/32 (0.093)

2.38

1/32 (0.031)

0.79

Over 12 [300]

+/- 1% of the specified outside diameter

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