ASTM A335 Alloy Seamless Steel Pipes
Primarily used in power generation boilers, refineries, petrochemical plants, and high-pressure process piping systems, ASTM A335 pipes handle critical applications such as steam lines, superheaters, heat exchangers, and hydrocarbon processing units. They operate effectively in temperatures ranging from 400°C to 650°C+ (depending on grade). The standard mandates strict requirements for chemical composition, heat treatment (normalization/tempering), mechanical properties (tensile/yield strength), hydrostatic testing, and non-destructive examination to ensure performance in demanding environments where corrosion, thermal stress, and pressure are major concerns.
Chemical Composition
Grade | P-5 | P-9 | P-11 | P-22 | P-91 | P-91 shall also | |
Element | UNS Designation | K41545 | S50400 | K11597 | K21590 | K91560 | |
Carbon | 0.15 max | 0.15 max | 0.05 – 0.15 | 0.05 – 0.15 | 0.08 – 0.12 | V at 0.18 – 0.25 | |
Manganese | 0.30 – 0.60 | 0.30 – 0.60 | 0.30 – 0.60 | 0.30 – 0.60 | 0.30 – 0.60 | N at 0.030 – 0.070 | |
Phosphorous, max | 0.025 | 0.025 | 0.025 | 0.025 | 0.02 | Ni at 0.40 max | |
Sulfur, max | 0.025 | 0.025 | 0.025 | 0.025 | 0.01 | Al at 0.02 max | |
Silicon | 0.50 max | 0.25 – 1.00 | 0.50 – 1.00 | 0.50 max | 0.20 -0.50 | Cb at 0.06 – 0.10 | |
Chromium | 4.00 – 6.00 | 8.00 – 10.00 | 1.00 – 1.50 | 1.90 – 2.60 | 8.00 – 9.50 | Ti at 0.01 max | |
Molybdenum | 0.45 -0.65 | 0.90 – 1.10 | 0.44 – 0.65 | 0.87 – 1.13 | 0.85 – 1.05 | Zr at 0.01 max | |
TensileTest
Seamless | ||||||
P-5 | P-9 | P-11 | P-22 | P-91 | P91 shall not have a hardness not exceeding 250 HB/265 HV [25HRC]. | |
Tensile Strength, min., psi | ||||||
ksi | 60 | 60 | 60 | 60 | 85 | |
MPa | 415 | 415 | 415 | 415 | 585 | |
Yield Strength, min., psi | ||||||
ksi | 30 | 30 | 30 | 30 | 60 | |
MPa | 205 | 205 | 205 | 205 | 415 | |
Other Mechanical Test
Transverse or Longitudinal Tension Test and Flattening Test, Hardness Test, or Bend Test | |
For material heat treated in a batch-type furnace, tests shall be made on 5% of the pipe from each treated lot. for small lots, at least one pipe shall be tested. | |
For material heat treated by the continuous process, tests shall be made on a sufficient number of pipe to constitute 5% of the lot, but in no case less than 2 pipe. | |
Notes for Hardness Test: | P91 shall not have a hardness not exceeding 250 HB/265 HV [25HRC]. |
Notes for Bend Test: | For pipe whose diameter exceeds NPS 25 and whose diameter to wall thickness ratio is 7.0 or less shall be subjected to the bend test instead of the flattening test. |
Other pipe whose diameter equals or exceeds NPS 10 may be given the bend test in place of the flattening test subject to the approval of the purchaser. | |
The bend test specimens shall be bent at room temperature through 180 without cracking on the outside of the bent portion. | |
The inside diameter of the bend shall be 1 inch [25 mm]. | |
Hydrostatic test | Each length of pipe shall be Hydro tested, at option of manufacture, nondestructive electric testing can be used. |
Heat Treatment
P5, P9, P11, and P22 | |||
Grade | Heat Treatment Type | Normalizing Temperature Range F [C] | Subcritical Annealing or Tempering Temperature Range F [C] |
P5 (b,c) | Full or Isothermal Anneal | ||
Normalize and Temper | ***** | 1250 [675] | |
Subcritical Anneal (P5c only) | ***** | 1325 – 1375 [715 – 745] | |
P9 | Full or Isothermal Anneal | ||
Normalize and Temper | ***** | 1250 [675] | |
P11 | Full or Isothermal Anneal | ||
Normalize and Temper | ***** | 1200 [650] | |
P22 | Full or Isothermal Anneal | ||
Normalize and Temper | ***** | 1250 [675] | |
P91 | Normalize and Temper | 1900-1975 [1040 – 1080] | 1350-1470 [730 – 800] |
Quench and Temper | 1900-1975 [1040 – 1080] | 1350-1470 [730 – 800] | |
Permissible Variation in Wall Thickness
NPS [DN] Designator | Tolerance, % from Specified | |
Over | Under | |
1/8 to 2 1/2 [6 to 65] incl., all t/D ratios | 20.00% | 12.50% |
Above 2 1/2 [65], t/D or = 5% | 22.50% | 12.50% |
Above 2 1/2 [65], t/D 5% | 15.00% | 12.50% |
(t = Specified Wall Thickness; D = Specified Outside Diameter) | ||
Elongation Requirement
Calculated Minimum Elongation Values | ||||
Elongation in 2 in. or 50 mm, min % | ||||
Wall Thickness | P5, P9, P11, P22 | P91 | ||
in. | mm | Longitudinal | Transverse | Longitudinal |
5/16 (0.312) | 8 | 30 | 20 | 20 |
9/32 (0.281) | 7.2 | 28 | 19 | 19 |
1/4 (0.250) | 6.4 | 27 | 18 | 18 |
7/32 (0.219) | 5.6 | 26 | 17 | |
3/16 (0.188) | 4.8 | 24 | 16 | |
5/32 (0.156) | 4 | 22 | 15 | |
7/8 (0.125) | 3.2 | 21 | 14 | |
3/32 (0.094) | 2.4 | 20 | 13 | |
1/18 (0.062) | 1.6 | 18 | 12 | |
Permissible Variations in Outside Diameter
NPS [DN] Designator | Over | Under | ||
in. | mm | in. | mm | |
1/8 to 1 1/2 [6 to 40], incl. | 1/64 (0.015) | 0.4 | 1/64 (0.015) | 0.4 |
Over 1 1/2 to 4 [40 to 100], incl. | 1/32 (0.031) | 0.79 | 1/32 (0.031) | 0.79 |
Over 4 to 8 [100 to 200], incl. | 1/16 (0.062) | 1.59 | 1/32 (0.031) | 0.79 |
Over 8 to 12 [200 to 300], incl. | 3/32 (0.093) | 2.38 | 1/32 (0.031) | 0.79 |
Over 12 [300] | +/- 1% of the specified outside diameter | |||
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